What is crevice corrosion?

Crevice corrosion occurs in confined spaces where stagnant solutions create a corrosive environment. This phenomenon occurs when metals, especially CRA's, are exposed to high chloride environments, like seawater. The protective oxide layer breaks down in these confined spaces, leading to aggressive localized corrosion. Over time, crevice corrosion leads to significant damage, equipment failure, costly repairs and safety hazards.

The real-world problems caused by crevice corrosion

Crevice corrosion is a significant risk to the longevity and safety of industrial equipment. Accurately predicting and preventing crevice corrosion is critical to maintaining operational efficiency and avoiding unexpected failures.

Corrosion in subsea oil and gas equipment

Subsea pipelines and wellheads that are made from duplex stainless steels are particularly vulnerable to crevice corrosion. The continuous exposure to chloride-rich seawater under low oxygen conditions leads to localized breakdown of the protective layer. Predicting the pH and chloride concentration within these crevices is essential for mitigating this risk.

Issues in reactors and storage tanks in chemical processing

Chemical plants process aggressive mixtures that exacerbate crevice corrosion, particularly in reactors and storage tanks. The chemical environments, including the dissolved metals concentration (e.g., Cr and Mo), can lead to significant localized corrosion. Predicting the corrosivity of these environments is crucial for preventing leaks and maintaining safety.

Reduced lifespan of heat exchangers in power generation and cooling systems

Crevice corrosion can occur in heat exchangers exposed to chloride-containing water. The aggressive nature of this water can lead to rapid corrosion and reduced efficiency of these units. Detailed analysis of the electrochemical conditions within these crevices is necessary to prevent such failures.

Proactively addressing crevice corrosion

Corrosion management strategies

Imagine having the capability to predict where and when crevice corrosion will occur in your systems, allowing you to implement preventive measures before significant damage occurs. By leveraging OLI advanced simulation solutions, you can model the exact thermodynamic and electrochemical conditions within crevices, giving you the insights needed to protect your assets and ensure operational reliability.

Predictive Corrosion Modeling

With the use of OLI Systems’ Mixed-Solvent Electrolyte (MSE) framework, you can accurately predict the aggressive properties of a crevice liquid, such as pH,  chloride concentration, metal hydrolysis and film stability. These are critical predictors of crevice corrosion initiation and propagation. An excellent example is predicting the anodic dissolution products in a chloride-rich environment, since this is an indicator of crevice corrosion risk potential.

Detailed Environmental Analysis

Understanding how your materials will react in specific environments is essential for preventing crevice corrosion. OLI’s software allows you to simulate the dissolution products of alloys under various environmental conditions, including temperature and chloride concentration. By analyzing the precipitation of corrosion products like NiCl2 6H2O or Cr(OH)3, you can make informed decisions about material selection and design modifications to extend the life of your equipment.

Take the next step toward securing your assets

Don’t let crevice corrosion compromise your operations. Protect your assets and ensure uninterrupted performance by leveraging advanced corrosion management software.